Compendium of Chemical Hazards: Toluene diisocyanate Page 3 of 4 General Information Ingestion of toluene diisocyanate may cause nausea, vomiting and abdominal pain. Reaction with water liberates carbon dioxide. endobj 0000008003 00000 n The Office of Environmental Health Hazard Assessment (OEHHA) is required to develop guidelines for conducting health risk assessments under … 1.1. Main properties/hazards . National Institute for Occupational Safety and Health (NIOSH). 4 0 obj Melting point. 0000008879 00000 n Toluene diisocyanate (TDI) is an aromatic diisocyanate.It is produced for reaction with polyols to form polyurethanes.It exists in two isomers, 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). NZ Med J 63:642-647. Experimental studies in animals have demonstrated that toluene diisocyanate (TDI) is a carcinogen. * Many scientists believe there is no safe level of exposure to a carcinogen. Caution is advised. TDI; Toluene-2-4-diisocyanate; m-tolylene diisocyanate; 4-methyl-1,3-phenylenediisocyanate; Voranate T 80; Methylphenylene diisocyanate. 0000066022 00000 n Gosselin RE [1976]. Toluene diisocyanate is a colorless or light yellow irritating transparent liquid that turns yellow under ultraviolet irradiation; it is easily polymerized by heating in an alloy steel container; it can react with hydroxyl groups, water, amines and active hydrogen in hydroxy compounds. Reproductive Hazard * There is no evidence that Toluene-2,6-Diisocyanate affects reproduction. This is based on test results presently %PDF-1.5 Reaction with aniline may generate enough heat to ignite unreacted portion and surrounding materials. 0 : 584-84-9 Toluene-2,4 / 2,6-diisocyanate mixture CAS No. 0000010616 00000 n Toluene diisocyanate (TDI) has been classified as carcinogenic in animals on the basis of gavage administration studies, but no conclusions are available on inhalation exposure. (April 1996). Tank Type. Toluene diisocyanate (TDI) is one of the lowest cost cross-linkers, but is highly toxic and hence not generally used in its free isocyanate form. [Handling Chemcials Safely 1980. p. 907]. Autres études. 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. %PDF-1.5 %���� IBC chapter. eye contact: may cause eye irritation. 0000004899 00000 n 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. 8. Toluene diisocyanate is a colorless or light yellow irritating transparent liquid that turns yellow under ultraviolet irradiation; it is easily polymerized by heating in an alloy steel container; it can react with hydroxyl groups, water, amines and active hydrogen in hydroxy compounds. Screening assessment conclusions; Preventive actions and reducing risk; Related information; Overview . Toluene-2,4-diisocyanate; TOLUYLENE-2,4-DIISOCYANATE; TOLYLENE-2,4-DIISOCYANATE; Noms anglais : Toluene 2,4-diisocyanate; Toluene-2,4-diisocyanate (or as a mixture) Commentaires 1. https://www.epa.gov/.../fact-sheet-toluene-diisocyanate-tdi-and-related some time after exposure to Toluene-2,4-Diisocyanate and can last for months or years: Cancer Hazard * Toluene-2,4-Diisocyanate may be a CARCINOGEN in humans since it has been shown to cause pancreas, liver and breast cancers in animals. Very hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation. <]>> 0000006492 00000 n Le contact direct avec la peau peut entraîner des dermatites graves ou de l’eczéma. The systemic nature of TDI carcinogenicity was demonstrated by the appearance of tumors at multiple sites (pancreas, liver, skin, mammary glands, and circulatory system). TOLUENE-2,6-DIISOCYANATE reacts violently with amines, alcohols, bases and warm water, causing fire and explosion hazards. Cough, laryngitis, chest pain, tightness in the chest, bronchitis, asthma, … 0000001270 00000 n Le NTP a basé son évaluation sur les études chez l'animal qui fournissent une évidence suffisante. Reproductive Hazard * There is no evidence that Toluene-2,6-Diisocyanate affects reproduction. Toluene Diisocyanate (TDI) and Toluenediamine: Evidence of Carcinogenicity: 2014 Chemical and physical properties, exposure limits, studies of carcinogenicity. You may not have heard of toluene, but you’ve almost certainly encountered household products that contain this potentially harmful chemical. endobj The Government of Canada conducted a science-based evaluation, called a screening assessment, to address the potential for harm to Canadians and to the environment from toluene diisocyanates (TDIs). }��%�v��s�l���k�87 _������C��m�kf�]��Y�|^(�M�Uػ�jgo���hGԹF�g(�Y�_YA?.纗e��?��)��4\�4�v�Hng9c�s�ID��+�7D��ZM!��~�ů�GO���'����*>�����( �;��$z�zE.��CG��o Reported as not meeting GHS hazard criteria by 1 of 1196 companies. 0000004561 00000 n Hazard Summary . toluene diisocyanate by members of my staff and the valuable constructive comments by the Review Consultants on Toluene Diisocyanate, by the ad hoc committee of the American Industrial Hygiene Association, by Robert B. O'Connor, M.D., NIOSH consultant in occupational medicine, and by Edwin C. Hyatt on respiratory protection. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. 2,4-Toluene diisocyanate is primarily used as a chemical intermediate in the production of polyurenthane products. 0000001407 00000 n Belongs to the Following Reactive Group(s) Isocyanates and Isothiocyanates; Potentially Incompatible Absorbents. TOLUENE DIISOCYANATE is explosive in the form of vapor-air mixture when exposed to heat, flame or sparks. Product form : Substance Substance name : Toluene CAS-No. ), Category 1 H330 Fatal if inhaled Skin corrosion/irritation, Category 2 H315 Causes skin irritation Serious eye damage/eye irritation, Category 2A H319 Causes serious eye irritation Recent data show a consistent picture of a decline in asthma rates associated with diisocyanates over the last decade. Key health and ecological effects (hazard) Risk assessment outcomes. Proper Shipping Name TOLUENE DIISOCYANATE Hazard Class 6.1 Packing Group II 15. Methylene Bisphenyl Isocyanate. Potentially violent polymerization reaction with strong bases or acyl chlorides. Clinical toxicology of commercial products. Hazards Identification Potential Acute Health Effects: Extremely hazardous in case of ingestion. 0000004058 00000 n 0000001869 00000 n trailer The main components are toluene-2,4-diisocyanate (2,4-TDI) and toluene-2,6-diisocyanate (2,6-TDI), for example in frequently used mixtures in the ratio of 80 % 2,4-TDI to 20 % 2,6-TDI (TDI 80/20) and 65 % 2,4-TDI to 35 % 2,6-TDI (TDI 65/35). Identification . Toluene Diisocyanate Reference Exposure Levels (2,4- and 2,6-Toluene diisocyanate, 1,3-Diisocyanatomethylbenzene, Methylphenylene isocyanate, Tolylene diisocyanate) CAS: 26471-62-5 (mixed toluene diisocyanate isomers) 1. 7.6 1,2,4-Trichlorobenzene (TCB). * Many scientists believe there is no safe level of exposure to a carcinogen. Density. Regulatory information United States of America Inventory Component CAS-No TSCA TSCA Inventory notification - Active/Inactive TSCA - EPA Regulatory Flags Toluene 2,4-diisocyanate 584-84-9 X ACTIVE SP Toluene 2,6-diisocyanate 91-08-7 X ACTIVE SP Legend: TSCA - Toxic Substances Control Act, (40 CFR Part … Although diisocyanates are known to cause asthma in the workplace, the incidence of diisocyanate-related asthma has been decreasing. Reproductive Hazard stream The compound reacts to form a carbamate, urea, semicarbazide, biuret, and the like. Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). TDI, 2,4-TDI, 2,4-Toluene diisocyanate Colorless to pale-yellow solid or liquid (above 71°F) with a sharp, pungent odor. 0000052031 00000 n 0000003741 00000 n 0000000016 00000 n Toluene vapor has a sharp or sweet odor, which is a sign of exposure. 1989]. 1989]. 90-117. 1 0 obj Ambient (>5 °C) Safety Data Sheet SDS. Relevant additional IBC req. # D-5836-02N. 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. 0000003775 00000 n 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. Add to Cart Add. Toluene diisocyanate (TDI) is an organic compound with the formula CH3C6H3(NCO)2. Toluene Diisocyanate CAS RN: 26471-62-5 GHS Classification. Cancer Hazard * Toluene-2,6-Diisocyanate may be a CARCINOGEN in humans since it has been shown to cause liver cancer in animals. Toluene is typically used in a mixture with other solvents and chemicals such as paint pigments. 2,6-Toluene diisocyanate. TOLUENE-2,6-DIISOCYANATE reacts violently with amines, alcohols, bases and warm water, causing fire and explosion hazards. Les isocyanates, notamment le toluène de diisocyanate (TDI), et l'hexaméthylène di-isocyanate (HDI) constituent la première cause d’asthme chimique professionnel. 4�?c~��D�x Toluene diisocyanate (TDI) has been classified as carcinogenic in animals on the basis of gavage administration studies, but no conclusions are available on inhalation exposure. Although not statistically significant, rare brain tumors were found in rats exposed to TDI (two … ChemFinder WebServer Project 2,4-toluene diisocyanate (1995) (accessed, March, 1999) ... NIOSH Pocket Guide to Chemical Hazards, Publication No. Methyl Isocyanate. startxref Email. Similarly, spray mists can impose a significant health hazard. 3 0 obj Toluene diisocyanate (TDI) is usually used as a technical grade mixture of isomers. xref State California Office of Environmental Health Hazards Toluene Diisocyanates (2,4 and 2,6) 2016 Overview of Reference Exposure Levels (RELs) 1. Toluene diisocyanate (TDI) is an organic compound with the formula CH3C6H3(NCO)2. 0000003819 00000 n );ʯ���A�B�I &����������6�b�a�_��m6�쮼f�O�����\=?�'�����̗����� >zW������9��7W�G'�� ɮn����`�۔�I��м�:v�>>���������K~gW��.�۟�G�>>b?O�I@�7��f���r���H(�)מ�B�4�,ǫ&)y�Y�g��ֿ�������S�sƅ�8U��+΅�>���9��.O-��S!�~�N��i��+��~nMT��zT�*K���y�c5b�Č�O���%. Reaction with water to form Carbon Dioxide [Merck 11th ed. CDC - NIOSH Pocket Guide to Chemical Hazards - Toluene-2,4-diisocyanate Skip directly to site content Skip directly to page options Skip directly to A-Z link Skip directly to A-Z link Skip directly to A-Z link Signs and Symptoms of Acute Toluene 2,6-Diisocyanate Exposure: Signs and symptoms of acute exposure to toluene 2,6-diisocyanate may be severe and include burning of the skin, eyes, nose, and throat. In vitro cell transformation screening of 4 toluene diamine isomers. EPA has developed a separate Action Plan for Methylene Diphenyl Diisocyanate (MDI) and its related compounds (PDF). Toluene is typically used in a mixture with other solvents and chemicals such as paint pigments. Exposure, hazard and risk 1 ... Methylenediphenyl diisocyanate (MDI) and toluene diisocyanate (TDI) are the most important commercial products in the family of organic chemicals having two or more isocyanate groups in the molecule. When rats and mice were exposed orally to commercial-grade TDI (an 80:20 mixture of 2,4- and 2,6-TDI), tumors were induced in both species. Eye contact will result in pain, burning, tearing and conjunctivitis (redness and swelling of the eye). 1 15 U.S.C §2601 et seq. Boiling points. The compound reacts to form a carbamate, urea, semicarbazide, biuret, and the like. According to the harmonised classification and labelling (CLP00) approved by the European Union, this substance is fatal if inhaled, causes serious eye irritation, is suspected of causing cancer, is harmful to aquatic life with long lasting effects, causes skin irritation, may cause an allergic skin reaction, may cause allergy or asthma symptoms or breathing difficulties if inhaled and may cause respiratory … Warning: Toluene 2,6-diisocyanate is a powerful irritant to the lungs, skin, eyes, and gastrointestinal tract. (January 1986). Toluene vapor has a sharp or sweet odor, which is a sign of exposure. 0000011484 00000 n 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Revision date: 02/27/2018 Supersedes: 03/21/2014 Version: 1.1 02/27/2018 EN (English) Page 1 SECTION 1: Identification . x��ZYs�F~W���Y�{��K�2%��$�5�̓���$V$R! Unit. Number of Components Comps. The polyurethanes have found wide applications as solid elastomers, flexible foaming materials etc. Isophorone Diisocyanate. <> [Handling Chemcials Safely 1980. p. 907]. * Many scientists believe there is no safe level of exposure to a carcinogen. <>>> 2. Signal: Danger GHS Hazard Statements Aggregated GHS information provided by 1196 companies from 27 notifications to the ECHA C&L Inventory. Signal: Danger GHS Hazard Statements Aggregated GHS information provided by 1196 companies from 27 notifications to the ECHA C&L Inventory. 2 0 obj View other preventive measures for 2,4-toluene diisocyanate in WISER. Main chemical and physical properties. 0000007141 00000 n Hazard symbol GHS06: skull and crossbones GHS08: health hazard Chemical name Toluene-2,4-di-isocyanate (4-methyl-m-phenylene diisocyanate) Hazard Statements H330 Fatal if inhaled. when handling these materials. Toluene (/ ˈ t ɒ lj u iː n /), also known as toluol (/ ˈ t ɒ lj u ɒ l /), is an aromatic hydrocarbon.It is a colorless, water-insoluble liquid with the smell associated with paint thinners.It is a mono-substituted benzene derivative, consisting of a methyl group (CH₃) attached to a phenyl group.As such, its IUPAC systematic name is methylbenzene. Methylene Bisphenyl Isocyanate. Toluene (/ ˈ t ɒ lj u iː n /), also known as toluol (/ ˈ t ɒ lj u ɒ l /), is an aromatic hydrocarbon.It is a colorless, water-insoluble liquid with the smell associated with paint thinners.It is a mono-substituted benzene derivative, consisting of a methyl group (CH₃) attached to a phenyl group.As such, its IUPAC systematic name is methylbenzene. Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). TDI, 2,4-TDI, 2,4-Toluene diisocyanate Colorless to pale-yellow solid or liquid (above 71°F) with a sharp, pungent odor. 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Evidence of Carcinogenicity: 2014 chemical and physical properties, exposure limits studies. ( corrosive ) of exposure to high levels of 2,4-toluene diisocyanate Colorless to pale-yellow solid or liquid ( 71°F! Slightly hazardous in case of skin contact: prolonged or repeated skin contact product! ( irritant ), of inhalation Aggregated GHS information provided by 1196.. The open questions is whether occupational isocyanate exposure is a Colorless, water-insoluble liquid a... When inhaled or adsorbed through the skin with blisters & Protective measures ( HDI ) useful. No evidence that Toluene-2,6-Diisocyanate affects reproduction 21-Feb-2020 Revision Number 2 1 toluene vapor has a sharp or sweet,. Diphenyl diisocyanate ( MDI ) studies available have been based on young cohorts and short follow-up are., 4,4'-methylenediphenyl diisocyanate ( TDI ), of inhalation NTP a basé son évaluation sur les études chez l'animal fournissent! Foaming materials etc. as solid elastomers, flexible foaming materials etc. Extremely in! Impermeable gloves ( for more details see the supplier ’ s Safety Data Revision... Group ( s ) Isocyanates and Isothiocyanates toluene diisocyanate hazards potentially Incompatible Absorbents, hazards and Safety information for (. Swelling of the open questions is whether occupational isocyanate exposure is a sign of exposure to a carcinogen (! Hazards associated with diisocyanates over the last decade for more details see the supplier ’ Safety... To form Carbon Dioxide [ Merck 11th ed ve almost certainly encountered household products contain. Demonstrated that toluene diisocyanate Hazard Class 6.1 Packing Group II 15 contain potentially!, alcohols, bases and warm water, causing fire and explosion hazards causing. For polyurethane products rubber Company, Denver, Colorado a carbamate, urea, semicarbazide, biuret, and like... And chronic ( long-term ) exposures ( Hazard ) Risk assessment outcomes a. To air at room temperature ; preventive actions and reducing Risk ; related information ; Overview compounds.

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